While I can appreciate the powerful diagnostics of Alpha OBD, I'm always leery of Bluetooth-based diagnostics, so I can't say for certain how accurate your readings are. I only started looking into AlphaOBD a month or so ago (so limited experience). I'm saying this while debating on upgrading my Autoenginuity Scan Tool to their wireless version (gotta catch up with the new stuff eventually I guess).
I always stress following procedures to a "T" since the code is not active - steps 2 and 3 no longer apply. But let's assume it is active:
1. Step 3 will not apply because the condition to move to step 3 is not present (ie voltage is not above 5.2 volts)
2. However, let's assume the conditions moved you to step 3:
2a. You stated you tested for voltage at Pin A, which is the TC connector. You should be testing for voltage on Pin 11 of the DTCM connector. The C2112 diagnostics lacked the diagram for the DTCM, so that is why I added it to the bottom. If Step 2 lead you to Step 3, and no voltage is present, then you would replace the DTCM because of an internal malfunction of the DTCM that is actively setting DTC C2112. The steps are walking you through to confirm a wiring issue or a hardware issue.
2b. Since DTC is not actively setting, except for under what seems to be very specific conditions (intermittent), it could be an internal solder joint expanding (heating up after 2 or 3 hours causing a loose connection), or it could be wiring.
The wiring diagram for 2010 shows an inline connector called C123 - I can not for the life of me find a solid wiring diagram for 2012. I know most of the harnesses from 2010-2012 are the same, but I can't find it either way. I also can't find additional info for C123, just that it exists (and it could be called a different number for 2012). I bring this up because that could lead you to another "pinch point" if you will for isolating loose or corroded pins and wires.
These trucks are super finicky when it comes to wiring and intermittent conditions. I hate it as I've been dealing with it for about 8 years or so (I just reset DTCs and keep on trucking)!
I'm willing to bet there is something between both connectors that is causing the DTC to set when you are up on the highway, and wires are vibrating and moving. It's best to have someone help you ohm check the wires, but unless you can find where and if that inline connector exists (C123 or the like), that may lead you to believe a wire is bad at either end, when it could be at that inline connector (again, if it actually exists).
3. As much as I like Chrysler products - Mopar TechAuthority (TA) has a lot to be desired when producing the service manuals, some stuff just doesn't make sense, so I question the viability of some of the info sometimes. As an example: The above procedures are for the DTCM, but it says to replace the FDCM (I fixed it once I realized TA's "copy and paste" mistake) and perform a powertrain verification on the DTCM - this is incorrect - those are two different modules and as far as I know, I haven't seen the FDCM on the diesel trucks.